研究業績

2024年

  1. M. Tanioka*, M. Mori, M. Harada, Y. Matsuya*,  S. Kamino*, Nonpolar selective emission (NPSE) of carbonyl-bridged rhodols, Chem. Commun., 60, 6407-6410 (2024).
  2. T. AijimaR Ueda, T. Nakane, F. Makino, Y. OhnishiJ. TokunagaK. Nakajima, S. Kamino, G. Kurisu, K. NambaH. NakataK. Mogi, H. Sajiki, S. Akai, Y. Sawama*, Versatile Biaryls and Fused Aromatics through Oxidative Coupling of Hydroquinones with (Hetero)Arenes., ChemistrySelect, 9, e202400647 (2024).
  3. M. Tanioka*, M. Oyama, K. Nakajima, M. Mori, M. Harada, Y. Matsuya*,  S. Kamino*, Coerulein B: a water-soluble and water-compatible near-infrared photoredox catalyst., Phys. Chem. Phys. Chem., 26, 4474-4479 (2024)
  4. M. Harada, S. Fujioka, S. Ansai, C. Wang, S. Kamino, K. Hirano*, M. Uchiyama*BN-Embedded Aromatic Hydrocarbon Synthesis via Nucleophilic Diboration Reactions, Org. Lett., 26, 247-251 (2024)

2023年

  1. M. Harada, M. Kutsuna, T. Kitamura, Y. Usui, M. Ujiki, Y. Nakamura, T. Obata, M. Tanioka, M. Uchiyama, D. Sawada, S. Kamino*, Nucleophile-triggered π-topological transformation: a new synthetic approach to near- infrared-emissive rhodamines, Chem. Eur. J., 29, e202301969 (2023).
  2. S. Kamino* and M. Uchiyama*, Xanthene-based functional dyes: towards new molecules operating in the near-infrared region, Org. Biomol. Chem., 21, 2458-2471 (2023). [Selected as a front cover]

2022年

  1. M. Tanioka*, A. Kuromiya, R. Ueda, T. Obata, A. Muranaka, M. Uchiyama, S. Kamino*, Bridged eosin Y: a visible and near-infrared photoredox catalyst, Chem. Commun., 58, 7825-7828 (2022).
  2. M. Tanioka, T. Ebihana, M. Uraguchi, H. Shoji, Y. Nakamura, R. Ueda, S. Ogura, Y. Wakiya, T. Obata, T. Ida, J. Horigome, S. Kamino*, Visualization of the photodegradation of a therapeutic drug by chemometric-assisted fluorescence spectroscopy, RSC Advances, 12, 20714-20720 (2022).

2021年

  1. N. Koga, M. Tanioka, S. Kamino* and D. Sawada*, Morpholine-Substituted Rhodamine Analogue with Multi-Configurational Switches for Optical Sensing of pH Gradient under Extreme Acidic Environments, Chem. Eur. J., 27, 3761-3765 (2021).
  2. T. Yamashiro, T. Abe*, M. Tanioka, S. Kamino, D. Sawada*, cis-3-Azido-2-methoxyindolines as safe and stable precursors to overcome the instability of fleeting 3-azidoindole, Chem. Commun., 57, 13381-13384 (2021).

2020年

  1. M. Harada, M. Tanioka, A. Muranaka*, T. Aoyama, S. Kamino and M. Uchiyama*, A remarkably air-stable quinodimethane radical cation, Chem. Commun., 56, 9565-9568 (2020).
  2. M. Tanioka, S. Kamino*, N. Koga, D. Sawada*, Stepwise structural and fluorescent colour conversion in rhodamine analogues based on light and acid stimulations, J. Mater. Chem. C, 8, 543-549 (2020).

2019年

  1. Y. Akamatsu, S. Kamino and D. Sawada*, Synthesis of a Tetracyclic Aminobenzimidazole Derivative via Tandem Cyclization of Triphenylguanidine, Heterocycles, 99, 815-819 (2019).
  2. R. Hosoda, S. Kamino*, M. Ueda, D. Sawada*, Syntheses and acid-stimulus responsiveness of aminobenzopyranoxanthene spiroethers, Heterocycles, 99, 820-824 (2019).
  3. 外部刺激応答性有機π電子系分子の開発と新奇な光機能の創出 神野伸一郎, 薬学雑誌, 139, 975-986 (2019).

2018年以前

  1. Y. Okamoto, M. Tanioka, A. Muranaka, K. Miyamoto, T. Aoyama, X. Ouyang, S. Kamino, D. Sawada and M. Uchiyama. Stable Thiele’s Hydrocarbon Derivatives Exhibiting Near- Infrared Absorption/Emission and Two-Step Electrochromism, J. Am. Chem. Soc., 140, 17857-17861, (2018).
  2. 外部刺激に応答して色と吸収・蛍光波長が大きく変化するクロミック分子の開発 神野伸一郎, 谷岡 卓, 澤田 大介, 有機合成化学協会誌, 78, 1066-1075 (2018).
  3. N. Fukino, S. Kamino, M. Takahashi and D. Sawada. Synthesis of Aminobenzopyranoxanthene with Nitrogen-Containing Fused-Rings, J. Org. Chem., 82, 13626-13631 (2017).
  4. K. Yamamoto, S. Kamino and D. Sawada. Direct C-H substitution reaction of anilides using hypervalent iodine and their regioselective issues, Tetrahedron Lett., 58, 3936-3938 (2017).
  5. M. Munekane, M. Ueda, S. Motomura, S. Kamino, H. Haba, Y. Yoshikawa, H. Yasui and S. Enomoto. Investigation of Biodistribution and Speciation Changes of Orally Administered Dual Radiolabeled Complex, Bis(5-chloro-7-[I-131]iodo-8-quinolinolato)[Zn-65]zinc, Biol. Pharm. Bull, 40, 510-515 (2017).
  6. S. Kamino, M. Tanioka, D. Sawada and S. Enomoto. Syntheses and Photophysical Properties of Aminobenzopyranoxanthene Dyes Containing Alkyl Chains at Amine moieties, Heterocycles, 95, 1167-1176 (2017).
  7. M. Tanioka, S. Kamino, A. Muranaka, Y. Shirasaki, Y. Ooyama, M. Uchiyama, S. Enomoto and D. Sawada. Water-Tunable Solvatochromic and Nanoaggregate Fluorescence: Dual Colour Visualisation and Quantification of Trace Water in Tetrahydrofuran, Phys. Chem. Phys. Chem., 19, 1209-1216 (2017).
  8. Y. Shirasaki, Y. Okamoto, A. Murananka, S. Kamino, D. Hashizume, D. Sawada and M.Uchiyama. Fused-Fluoran Leuco Dyes with Large Color-Change Derived from Two-Step Equilibrium: iso-Aminobenzopyranoxanthenes, J. Org. Chem., 81, 12046-12051 (2016).
  9. Y. Matsuura, M. Ueda, Y. Higaki, K. Watanabe, S. Habara, S. Kamino, H. Saji and S. Enomoto. Noninvasive evaluation of nicotinic acetylcholine receptor availability in mouse brain using single-photon emission computed tomography with [123I]5IA, Nucl. Med. Biol., 43, 372-378 (2016).
  10. T. Miyamoto, Y. Fukino, S. Kamino, M. Ueda and S. Enomoto. Enhanced stability of Cu2+-ATCUN complexes under physiologically relevant conditions by insertion of structurally bulky and hydrophobic amino acid residues into the ATCUN motif, Dalton Trans., 45, 9436-9445 (2016).
  11. T. Yamaguchi, M. Hoshino, K. Miyachi, S. Kamino, R. Nakahara, M. Doi, M. Asano, H. Matsumura and Y. Fujita. Crystal Structure of o-Carboxyphenylfluorone as a Multifunctional Dye, X-RAY STRUCTURE ANALYSIS ONLINE, 32, 9-10 (2015).
  12. M. Munekane, S. Motomura, S. Kamino, M. Ueda, H. Haba, Y. Yoshikawa, H. Yasui M. Hiromura and S. Enomoto. Visualization of biodistribution of Zn complex with antidiabetic activity using semiconductor Compton camera GREI, Biochem Biophys Rep., 5, 211-215 (2015).
  13. M. Tanioka, S. Kamino, A. Muranaka, Y. Ooyama, H. Ota, Y. Shirasaki, J. Horigome, M. Ueda, M. Uchiyama, D. Sawada and S. Enomoto. Reversible Near-Infrared/Blue Mechanofluorochromism of Aminobenzopyranoxanthene, J. Am. Chem. Soc., 137, 6436-6439 (2015).
  14. T. Miyamoto, S. Kamino, A. Odani, M. Hiromura and S. Enomoto. Development of new peptide-based chelating agents for site-specific radiolabeling with 64Cu, Yakugaku Zasshi J-Pharm. Soc. Jpn., 132, 953-958 (2014).
  15. M. Hoshino, S. Kamino, M. Doi, S. Takada, S. Mitani, R. Yanagihara, M. Asano, T. Yamaguchi and Y. Fujita. Spectrophotometric Determination of Hydrogen Peroxide with Osmium (VIII) and m-Carboxyphenylfluorone, Spectrochim. Acta. A., 117, 814-816 (2014).
  16. T. Miyamoto, S. Kamino, A. Odani, M. Hiromura and S. Enomoto. Basicity of N-terminal Amine in ATCUN Peptide Regulates Stability Constant of Albumin-like Cu2+ Complex, Chem. Lett., 42, 1099-1101 (2013).
  17. Y. Shirasaki, S. Kamino, M. Tanioka, K. Watanabe, Y. Takeuchi, S. Komeda and S. Enomoto. New Aminobenzopyranoxanthene-Based Colorimetric Sensor for Cu2+ with Dual-Color Signal Detection System, Chem. Asian J., 8, 2609-2613 (2013).
  18. S. Kamino, A. Muranaka, M. Murakami, A. Tatsumi, N. Nagaoka, Y. Shirasaki, K. Watanabe, K. Yoshida, J. Horigome, S. Komeda, M. Uchiyama and S. Enomoto. A Red-Emissive aminobenzopyrano-xanthene Dye: Elucidation of Fluorescence Emission Mechanism in Solution and Aggregate State, Phys. Chem. Chem. Phys., 15, 2131-2140 (2013).
  19. M. Taniguchi, A. Fukunaka, M. Hagihara, K. Watanabe, S. Kamino, T. Kambe, S. Enomoto and M. Hiromura. Essential Role of the Zinc Transporter ZIP9/SLC39A9 in Regulating the Activations of Akt and Erk in B-Cell Receptor Signaling Pathway in DT40 Cells, PLoSOne, 8, e58022 (2013).
  20. S. Kadowaki, M. Munekane, Y. Kitamura, M. Hiromura, S. Kamino, Y. Yoshikawa, H. Saji and S. Enomoto. Development of new zinc dithiosemicarbazone complex for use as oral antidiabetic agent, Biol. Trace Elem. Res., 154, 111-119 (2013).
  21. M. Hoshino, S. Kamino, S. Mitani, M. Asano, T. Yamaguchi and Y. Fujita. Spectrophotometric determination of titanium with o-carboxyphenylfluorone in cationic micellar media, and its equilibrium and kinetic studies, Talanta, 15, 2339-2343 (2011).
  22. M. Hoshino, S. Kamino, S. Takada, M. Ijyuin, M. Nakanishi, M. Naito, M. Asano, T. Yamaguchi and Y. Fujita. Determination of Trace Aluminum by Fluorescence Quenching with m-Carboxyphenylfluorone as Analytical Reagent, Anal. Sci., 27, 659-662 (2011).
  23. K. Higashkawa, N. Akada, K. Yagi, K. Watanabe, S. Kamino, Y. Kanayama, M. Hiromura and S. Enomoto. Exploration of Target Molecules for Molecular Imaging of Inflammatory Bowel Disease, Biochem. Biophy. Res. Commun., 410, 416-421 (2011).
  24. S. Kamino, Y. Horio, A. Tatsumi, S. Komeda, J. Horigome, K. Minoura, H. Ichikawa, T. Yamaguchi, Y. Usami, S. Hirota, S. Enomoto and Y. Fujita. A new class of rhodamine luminophores: design, syntheses and aggregation-induced emission enhancement, Chem. Commun., 46, 2013-2015 (2010).
  25. S. Kamino, Y. Kawamae, M. Ijyuin, S. Takada, T. Yamaguchi, M. Doi and Y. Fujita. Synthesis, spectral study and crystal structure of a fluorescein derivative, p-methoxycarbonylphenyl fluorone, Chem. Pharm. Bull., 57, 1405-1408 (2009).
  26. T. Yamaguchi, M. Samma, S. Kamino, M. Matsushita, T. Hashimoto and Y. Fujita. Spectrophotometric Determination of Copper(II) with o-Bromophenylfluorone, Anal. Sci., 25, 1457-1460 (2009).
  27. S. Kamino, H. Ichikawa, S. Wada, Y. Horio, Y. Usami, T. Yamaguchi, T. Koda, A. Harada, K. Shimanuki, M. Arimoto, M. Doi and Y. Fujita. Design and Synthesis of Regioisomerically Pure Unsymmetrical Xanthene Derivatives for Staining Live Cells and their Photochemical Properties, Bioorg. Med. Chem. Lett., 18, 4380-4384 (2008).
  28. K. Miyachi, K. Moriyama, T. Yamaguchi, H. Tominaga, S. Kamino and Y. Fujita. Spectrophotometric Determination of Spermine and Related Compounds Using, Anal. Sci., 23, 1103-1107 (2007).
  29. T. Yamaguchi, K. Hasegawa, S. Kamino, K. Miyachi, H. Tominaga and Y. Fujita. Spectrophotometric Determination of Uric Acid Based on Fading of o-Hydroxyhydroquinonephthalein-palladium(II)-hexadecyltrimethyl-ammonium Complex, Anal. Sci., 23, 223-226 (2007).
  30. S. Kamino, M. Doi, T. Yamaguchi, H. Tominaga, E. Amano, S. Umehara, M. Naito, C. Yamazaki and Y. Fujita. Crystal Structure of o-Sulfophenylfluorone as a Bioquantification Probe, Anal. Sci., 22, x35-x36 (2006).
  31. S. Kamino, T. Yamaguchi, T. Mori, M. Miyamoto, Y. Kusumi and Y. Fujita. Spectrophotometric Determination of Aluminum with m-Carboxyphenylfluorone, a Novel Chemical Probe, and Its Application, Anal. Sci., 21, 1549-1542 (2005).
  32. T. Yamaguchi, E. Amano, S. Kamino, S. Umehara, C. Yanaihara and Y. Fujita. Spectrophotometirc Determination of Urinary Protein with o-Sulfophenylfluorone-Metal Complex, Anal. Sci, 21, 1237-1240 (2005).

愛知学院大学 薬学部

生体有機化学講座

〒464-8650 名古屋市千種区楠元町1-100

TEL: 052-757-6768

E-mail : skamino[at]dpc.agu.ac.jp

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